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- Title
- Magnetic and Transport Properties of Electrochemically Oxidized Polyacetylene.
- Creator
-
Reynolds, John, Schlenoff, Joseph B., Chien, James C. W.
- Abstract/Description
-
The magnetic and transport properties of polyacetylene electrochemically oxidized in the presence of perchlorate ion have been determined. Room temperature dc conductivity is unaffected by doping between 10 -6
Show moreThe magnetic and transport properties of polyacetylene electrochemically oxidized in the presence of perchlorate ion have been determined. Room temperature dc conductivity is unaffected by doping between 10 -6 < y -< 10 -3~. A rapid conductivity increase occurs with increasing dopant level having a midpoint of transition at ca. y - 8 x 10-3 By comparison, the change in thermopower vs. y is sharper taking place within a tenfold increase in y with a midpoint at ca. y - 3 x 10 -3. The unparied spin concentrations remain constant as dopant concentration increases before the onset of a Dysonian lineshape at ca. y -= 10 -2. The results are interpreted as the melting of a glassy carrier state causing the sharp change of transport properties. A phase separation into metallic domains occurs at y = ca. 10 -~. Side reactions involving the electrolyte complicate the electrochemistry of po]yacetylene.
Show less - Date Issued
- 1985
- Identifier
- FSU_migr_chm_faculty_publications-0008, 10.1149/1.2114027
- Format
- Citation
- Title
- A National Survey of the Use of Discover and SIGI: Technical Report No. 1.
- Creator
-
Sampson Jr., James P., Shahnasarian, Michael, Reardon, Robert C.
- Abstract/Description
-
This report describes a national survey of 677 institutions using DISCOVER and SIGI as of June 1984. The goal was to produce a generic description of the present use of these systems. A return rate of 64.7% (N=438) was obtained to the 30 item questionnaire. Survey results are presented and discussed on the following topics: (1) system(s) currently in use, (2) institutional characteristics, (3) system configuration, (4) integration with other services, (5) counselor and staff intervention, (6)...
Show moreThis report describes a national survey of 677 institutions using DISCOVER and SIGI as of June 1984. The goal was to produce a generic description of the present use of these systems. A return rate of 64.7% (N=438) was obtained to the 30 item questionnaire. Survey results are presented and discussed on the following topics: (1) system(s) currently in use, (2) institutional characteristics, (3) system configuration, (4) integration with other services, (5) counselor and staff intervention, (6) usage statistics for all users, (7) system management, (8) system implementation, and (9) potential needs. The report includes 15 tables and four appendices. The authors acknowledge the support and assistance provided by personnel at the American College Testing Program and the Education Testing Service in the completion of this survey.
Show less - Date Issued
- 1985-04-01
- Identifier
- FSU_libsubv1_scholarship_submission_1525273501_41c11166, 10.17125/fsu.1525273501
- Format
- Citation
- Title
- A National Comparison of the Use of Discover and SIGI.
- Creator
-
Sampson Jr., James P., Shahnasarian, Michael, Reardon, Robert C.
- Abstract/Description
-
This report describes the results of a nationwide comparative study of the 677 sites using DISCOVER or SIGI as of June 1984. Software-based and institutionally-based factors influencing system use were explored. The former included theoretical bases, ease of software usage, and developer's implementation assistance, while the latter included staff competence, organizational dynamics, financial resources, clientele, implementation plan, and system integration with other activities and...
Show moreThis report describes the results of a nationwide comparative study of the 677 sites using DISCOVER or SIGI as of June 1984. Software-based and institutionally-based factors influencing system use were explored. The former included theoretical bases, ease of software usage, and developer's implementation assistance, while the latter included staff competence, organizational dynamics, financial resources, clientele, implementation plan, and system integration with other activities and facilities. The sample included 408 respondents (60.3%) to those surveyed. Multivariate log-linear models were used to analyze data with fiver areas of systems use, and univariate analyses were used in two other areas. Results suggested that institutionally-based factors, not software-based factors, were largely determining how DISCOVER and SIGI were used. However, it was noted that software-by researchers, developers, and practitioners in order to maximize the impact of computer-assisted career guidance systems. The report includes 10 tables and one appendix. The authors acknowledge the support and assistance of personnel at the American College Testing Program and the Educational Testing Service in completing this research.
Show less - Date Issued
- 1986-03-01
- Identifier
- FSU_libsubv1_scholarship_submission_1525275753_7936e951, 10.17125/fsu.1525275753
- Format
- Citation
- Title
- A Differential Feature Cost Analysis of Discover for Adult Learners and SIGI Plus: Technical Report Number 4.
- Creator
-
Sampson Jr., James P., Domkowski, Dorothy, Peterson, Gary W., Reardon, Robert C.
- Abstract/Description
-
This report was prepared for the Clearinghouse for Computer-Assisted Guidance Systems at Florida State University. The Clearinghouse was established to provide current and readily accessible information relevant to selecting, implementing, and evaluating computer-assisted career guidance systems. The contents of this report consist primarily of a complete descriptive listing of the features and costs of DISCOVER AL and SIGI PLUS. The information presented in this paper was gathered from the...
Show moreThis report was prepared for the Clearinghouse for Computer-Assisted Guidance Systems at Florida State University. The Clearinghouse was established to provide current and readily accessible information relevant to selecting, implementing, and evaluating computer-assisted career guidance systems. The contents of this report consist primarily of a complete descriptive listing of the features and costs of DISCOVER AL and SIGI PLUS. The information presented in this paper was gathered from the manuals provided by the respective firms, American College Testing Program (DISCOVER AL) and Educational Testing Service (SIGI PLUS), interviews with ACT and ETS staff members, as well as the collective experiences of the authors as they themselves and their clients interacted with the systems. The criteria used in this analysis are based on the work of Harris-Bowlsbey (1983), Katz and Shatkin (1983), Maze (1984), Maze and Cummings (1982) and Riesenberg (1983). A draft of this report was sent to developers of the two systems, and their comments were used by the authors in preparing this final document.
Show less - Date Issued
- 1986-03-01
- Identifier
- FSU_libsubv1_scholarship_submission_1525277487_14d3eb25, 10.17125/fsu.1525277487
- Format
- Citation
- Title
- Sanitary pads for men.
- Creator
-
Lipner, Harry
- Abstract/Description
-
Sanitary pads for men are disposable in a storage mode in which they are flat and non-overlapping for easy carrying in pockets. The sanitary pads may be folded in order to form generally semi-cylindrical portions which envelop the wearer's penis and prevent embarrassment to incontinent men. In the storage or carrying mode, the pad may alternately be T-shaped or constructed in a generally rectangular shape. Adhesive means, such as double sided tape, or fabric loop and hook fasteners may be...
Show moreSanitary pads for men are disposable in a storage mode in which they are flat and non-overlapping for easy carrying in pockets. The sanitary pads may be folded in order to form generally semi-cylindrical portions which envelop the wearer's penis and prevent embarrassment to incontinent men. In the storage or carrying mode, the pad may alternately be T-shaped or constructed in a generally rectangular shape. Adhesive means, such as double sided tape, or fabric loop and hook fasteners may be used to secure the pads in proper position. The pads are a layered structure including an inner relatively thick layer of absorbent material, a water barrier layer made of plastic, and an outer relatively thin absorbent layer.
Show less - Date Issued
- 1986-03-18
- Identifier
- FSU_uspto_4576599, 4576599, 505970, 06/609651, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Use of Computer Assisted Career Guidance with Prior Cognitive Restructuring Technical Report Number 3.
- Creator
-
Shahnasarian, Michael, Peterson, Gary W.
- Abstract/Description
-
Cognitive structuring was implemented by showing 30 subjects a 10-minute videotape that presented Holland's (1985) model of the world of work before they used an interactive computer assisted guidance system (DISCOVER). The effect of prior structuring was assessed in terms of a subject's representation of the world of work, occupational certainty and vocational identity. The subjects were volunteer clients who came to a university career resource center for vocational counseling. Two...
Show moreCognitive structuring was implemented by showing 30 subjects a 10-minute videotape that presented Holland's (1985) model of the world of work before they used an interactive computer assisted guidance system (DISCOVER). The effect of prior structuring was assessed in terms of a subject's representation of the world of work, occupational certainty and vocational identity. The subjects were volunteer clients who came to a university career resource center for vocational counseling. Two treatment groups and a control group were used: pretest, cognitive structuring, and DISCOVER; pretest and DISCOVER; and DISCOVER only. The results indicated that subjects who assimilated the Holland model prior to using DISCOVER were more homogeneous in sorting 36 randomly selected occupations into related clusters, and were more homogeneous in the number of occupational alternatives they listed on a posttest. Subjects who used DISCOVER without cognitive structuring became significantly more assured of their vocational identity (i.e., goals, interests, personality), while the cognitive structuring group did not become so assured. Occupational certainty was unaffected by any treatment. The cognitive structuring experience prior to subject's use of DISCOVER encouraged them to add occupations to consider when they had a few alternatives and to eliminate occupations to consider when they had many.
Show less - Date Issued
- 1986-05-01
- Identifier
- FSU_libsubv1_scholarship_submission_1525276595_fa2576cf, 10.17125/fsu.1525276595
- Format
- Citation
- Title
- Serial bearing assembly.
- Creator
-
Li, Paul Z.
- Abstract/Description
-
Bearing assemblies use serial bearings in order to extend the operational speeds for the bearings. Speed distribution planetary gears are mounted upon an intermediate ring disposed between two other rings. Each of the rings has bearing surfaces which are separated from adjacent bearing surfaces by ball-bearings or other bearings. The planetary gears mesh with gear teeth upon the first and second rings so as to cause rotation of the intermediate ring at a speed intermediate the relative speed...
Show moreBearing assemblies use serial bearings in order to extend the operational speeds for the bearings. Speed distribution planetary gears are mounted upon an intermediate ring disposed between two other rings. Each of the rings has bearing surfaces which are separated from adjacent bearing surfaces by ball-bearings or other bearings. The planetary gears mesh with gear teeth upon the first and second rings so as to cause rotation of the intermediate ring at a speed intermediate the relative speed between the two other rings. The speed distribution planetary gears may be used in a serial thrust bearing assembly serial radial bearing assembly, or a serial radial thrust bearing assembly.
Show less - Date Issued
- 1986-10-21
- Identifier
- FSU_uspto_4618271, 4618271, 533931, 06/807659, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- The Cyclic Voltammetry of Pristine, Isomerized, Deuterated, and Partially Hydrogenated "P-Type" Polyacetylene.
- Creator
-
Schlenoff, Joseph B., Chien, James C. W.
- Abstract/Description
-
The cyclic voltammetry of ultrathin fihns of polyacetylene comprised of 2-3 nm micro fibrils and their aggregate 20 nm fibrils in methylene chloride, acetonitrile, propylene carbonate, and sulfo]ane shows many similarities, including a background oxidation of electrolyte that leads to serious coulombic inefficiency in rechargeable polyacetylene battery applications. Reversible charging in neutral aqueous solution is limited by the poor separation between the reversible and irreversible...
Show moreThe cyclic voltammetry of ultrathin fihns of polyacetylene comprised of 2-3 nm micro fibrils and their aggregate 20 nm fibrils in methylene chloride, acetonitrile, propylene carbonate, and sulfo]ane shows many similarities, including a background oxidation of electrolyte that leads to serious coulombic inefficiency in rechargeable polyacetylene battery applications. Reversible charging in neutral aqueous solution is limited by the poor separation between the reversible and irreversible oxidations. Comparison of ultrathin and free-standing 100 ~m thick films showed they have the same maximum reversible doping level and thus energy density of 280 Wh/kg. Pristine, isomerized, deuterated, and hydrogenated [CH].,. show similar electrochemistry. Both n and p-type chemical doping caused isomerization of cis-[CHL to trans-[CH]~.
Show less - Date Issued
- 1987
- Identifier
- FSU_migr_chm_faculty_publications-0007, 10.1149/1.2100848
- Format
- Citation
- Title
- The Impact of DISCOVER and SIGI on the Career Decision Making of College Students: Technical Report No. 5.
- Creator
-
Sampson, James P, Reardon, Robert C, Shahnasarian, Michael, Peterson, Gary W, Ryan-Jones, Rebecca, Lenz, Janet G
- Abstract/Description
-
The purpose of this research was to compare two widely used computer-assisted career guidance (CACG) systems, DISCOVER and SIGI. The goals were to: 1) assist practitioners in learning more about the benefits of using a CACG system as a component of total program services; 2) assist CACG system developers in revising software and support materials to more fully meet the needs of practitioners and users; and 3) assist researchers in planning further investigations concerning the optimal use of...
Show moreThe purpose of this research was to compare two widely used computer-assisted career guidance (CACG) systems, DISCOVER and SIGI. The goals were to: 1) assist practitioners in learning more about the benefits of using a CACG system as a component of total program services; 2) assist CACG system developers in revising software and support materials to more fully meet the needs of practitioners and users; and 3) assist researchers in planning further investigations concerning the optimal use of this technology. This technical report includes three separate studies designed to answer three different research questions. A sample of undergraduate psychology students was used for all three studies.
Show less - Date Issued
- 1987-02-01
- Identifier
- FSU_libsubv1_scholarship_submission_1525881042_a9d2505a, 10.17125/fsu.1525881042
- Format
- Citation
- Title
- Serial safety bearing.
- Creator
-
Li, Paul Z.
- Abstract/Description
-
Serial safety bearing assembly includes two concentric bearing sets and an actuatable device for selectively switching to engage either the inner or the outer of the two concentric bearing sets upon failure of one set or to alternate to first one set and then the other set thus to prolong the working life of the two concentric bearings.
- Date Issued
- 1987-05-12
- Identifier
- FSU_uspto_4664539, 4664539, 533931, 06/829080, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Method of removing SO.sub.2, NO.sub.X and particles from gas mixtures using streamer corona.
- Creator
-
Mizuno, Akira, Clements, Judson S.
- Abstract/Description
-
A method for converting sulfur dioxide and/or nitrogen oxide gases to acid mist and or particle aerosols is disclosed in which the gases are passed through a streamer corona discharge zone having electrodes of a wire-cylinder or wire-plate geometry.
- Date Issued
- 1987-09-22
- Identifier
- FSU_uspto_4695358, 4695358, 586388, 06/796268, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- A Comparison of the Effectiveness of Three Computer-Assisted Career Guidance Systems on College Students' Career Decision Making Processes: Technical Report No. 6.
- Creator
-
Peterson, Gary W, Ryan-Jones, Rebecca E, Sampson, James P, Reardon, Robert C, Shahnasarian, Michael
- Abstract/Description
-
The Computer-Assisted Career Guidance Evaluation Form, was developed to evaluate the effectiveness of CACG systems in performing three vital functions in career decision-making. This instrument was subsequently used to compare the effectiveness of DISCOVER, SIGI, and SIGI PLUS using 132 subjects from two cohort groups of students in an introductory psychology course. After finishing their assigned system, subjects completed the Computer-Assisted Career Guidance Evaluation Form, My Vocational...
Show moreThe Computer-Assisted Career Guidance Evaluation Form, was developed to evaluate the effectiveness of CACG systems in performing three vital functions in career decision-making. This instrument was subsequently used to compare the effectiveness of DISCOVER, SIGI, and SIGI PLUS using 132 subjects from two cohort groups of students in an introductory psychology course. After finishing their assigned system, subjects completed the Computer-Assisted Career Guidance Evaluation Form, My Vocational Situation (MVS) by Holland, Daiger, & Power (1980a), and the Occupational Alternatives Question (OAQ) (Zener & Schunelle, 1972). Results of the analysis of the data showed that all three CACG systems were rated positively. However, subjects who expressed a need for career information rated all three CACG systems significantly more effective (p < .001) in developing and evaluating career options than those subjects who perceived no need for information. Further, Subjects who were "undecided" about their career direction found SIGI PLUS significantly more helpful for obtaining self knowledge and occupational knowledge (p < .05), and more rewarding and enjoyable (p < .03). The results suggested that perceived effectiveness of CACG systems may be related to the state of client career decidedness (OAQ) and their need for career information (MVS).
Show less - Date Issued
- 1987-12-01
- Identifier
- FSU_libsubv1_scholarship_submission_1525882239_332a4eb4, 10.17125/fsu.1525882239
- Format
- Citation
- Title
- Computer-Assisted Career Guidance and the Adult Learner - Two Case Studies: Technical Report No. 8.
- Creator
-
Metzger, Elaine I, Sampson, Jame P, Reardon, Robert C
- Abstract/Description
-
The decision to seek career counseling services as an adult arises from a complex interaction of past experiences, current career development, and expectations for assistance. This study explored how these multiple motivations impact the service delivery of computer-assisted career guidance systems. The subjects were selected from adults who had sought services from a university-based career center and who were voluntarily participating in a research project designed to collect data on this...
Show moreThe decision to seek career counseling services as an adult arises from a complex interaction of past experiences, current career development, and expectations for assistance. This study explored how these multiple motivations impact the service delivery of computer-assisted career guidance systems. The subjects were selected from adults who had sought services from a university-based career center and who were voluntarily participating in a research project designed to collect data on this population. The subjects selected for this qualitative component of the study were chosen on the basis of the following factors: sex, age, head-of-household, anticipation of career change, interest in exploring career options, willingness to use a computer-assisted career counselor, and willingness to complete a contract for service provision. The study was intended as a process of exploration and discovery. As such, open-ended interviews were conducted prior to, during, and after each subject's computer experience. It was found that the adult subjects participating in this qualitative study differed in terms of the complexity and time frame for their career decision making in comparison to "typical" adolescents and young adults who receive services from university-based career centers. The subjects had expectations that they receive professional assistance that would help in: 1) structuring the career decision making process; 2) clarifying self-knowledge; and 3) gaining access to career information resources. The extent to which this expectation was met varied with each subject. Implications for the practice and for future research have been presented to stimulate further exploration in this area of career guidance for adults.
Show less - Date Issued
- 1988-03-01
- Identifier
- FSU_libsubv1_scholarship_submission_1525885695_1b4318ba, 10.17125/fsu.1525885695
- Format
- Citation
- Title
- A Comparative Analysis of the Impact of Two Generations of a Computer-Assisted Career Guidance System - SIGI and SIGI PLUS: Technical Report No. 7.
- Creator
-
Reardon, Robert C, Sampson, James P, Ryan-Jones, Rebecca E, Peterson, Gary W, Shahnasarian, Michael
- Abstract/Description
-
A study was conducted to examine the comparative impact of two generations of a computer-assisted career guidance system, SIGI and SIGI PLUS, on the career decidedness, vocational identity, and user perceptions of 64 college students. Students from an introductory psychology class who expressed interest in an experiment that involved receiving career guidance services were randomly assigned to either SIGI or SIGI PLUS. The Occupational Alternatives Question, and My Vocational Situation were...
Show moreA study was conducted to examine the comparative impact of two generations of a computer-assisted career guidance system, SIGI and SIGI PLUS, on the career decidedness, vocational identity, and user perceptions of 64 college students. Students from an introductory psychology class who expressed interest in an experiment that involved receiving career guidance services were randomly assigned to either SIGI or SIGI PLUS. The Occupational Alternatives Question, and My Vocational Situation were completed pre- and post-treatment while the SIGI or SIGI PLUS Evaluation Form (a measure of user perceptions) was completed post-treatment. After the completion of initial post-testing, students then used the second system and completed the Comparative Computer Rating Form which involved a direct bipolar comparison of the two systems. A series of multivariate and univariate statistical analyses revealed that users rated SIGI and SIGI PLUS equally positive for their effectiveness in obtaining self and occupational information (Analysis), viable career options (Synthesis), and in attractiveness of interaction with the computer (Synthesis), and in attractiveness of interaction with the computer (Computer Effect). Persons with initial information needs rated both CACG systems significantly higher (p < .05) on the Analysis scale than users without needs for information. Students' level of vocational identity increased significantly (p = .006) as a result of using SIGI and SIGI PLUS. Students with low initial vocational identity were more likely to increase their vocational identity if they used SIGI PLUS, than if they used SIGI. SIGI and SIGI PLUS appear equally capable of satisfying users' needs for information. Finally, when the 63 students were asked to indicate their overall preference for one of the two CACGS used, 24 or 38% preferred SIGI, while 39 or 62% preferred SIGI PLUS. Discussion of these results explored the differential impact of SIGI and SIGI PLUS and the equivalence of CACG systems. Specific implications for practice, system development, and future research are also provided.
Show less - Date Issued
- 1988-05-01
- Identifier
- FSU_libsubv1_scholarship_submission_1525884247_0237e588, 10.17125/fsu.1525884247
- Format
- Citation
- Title
- Apparatus for measuring fluid flow.
- Creator
-
Li, Paul Z.
- Abstract/Description
-
Apparatus for measuring flow rate and flow direction of a fluid comprises an elongated stem coaxially disposed and supported within an elongated housing, a small diameter spherical probe connected to an end of the stem which projects through an opening in the housing for transmitting to the stem forces exerted on the probe by the flowing fluid, and a sensor for detecting the forces transmitted to the stem and for producing electrical signals representative of a measurement of the flowing...
Show moreApparatus for measuring flow rate and flow direction of a fluid comprises an elongated stem coaxially disposed and supported within an elongated housing, a small diameter spherical probe connected to an end of the stem which projects through an opening in the housing for transmitting to the stem forces exerted on the probe by the flowing fluid, and a sensor for detecting the forces transmitted to the stem and for producing electrical signals representative of a measurement of the flowing fluid. The apparatus may detect forces exerted on the probe in one, two or three orthogonal directions, thereby providing output signals corresponding to the components of a vector representation of the fluid flow.
Show less - Date Issued
- 1988-12-06
- Identifier
- FSU_uspto_4788869, 4788869, 533931, 06/879628, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Transport, magnetic, and optical properties of electrochemically doped poly(1, 4-dimethoxy phenylene vinylene).
- Creator
-
Schlenoff, Joseph B., Obrzut, Jan, Karasz, F.
- Abstract/Description
-
A coordinated study on electrochemical, magnetic, optical, and transport properties of poly(1, 4- dimethoxy phenylene vinylene) (PDMPV) using in situ electrochemical doping techniques is presented. Properties are correlated through a common axis of applied voltage. Electrochemical doping shows approx. 100% Coulombic efficiency up to an applied potential of 3.8 V versus lithium in propylene carbonate electrolyte. Conductivity increases in a reversible manner to a maximum of 250 0 ' cm ' and an...
Show moreA coordinated study on electrochemical, magnetic, optical, and transport properties of poly(1, 4- dimethoxy phenylene vinylene) (PDMPV) using in situ electrochemical doping techniques is presented. Properties are correlated through a common axis of applied voltage. Electrochemical doping shows approx. 100% Coulombic efficiency up to an applied potential of 3.8 V versus lithium in propylene carbonate electrolyte. Conductivity increases in a reversible manner to a maximum of 250 0 ' cm ' and an applied potential of 3.9 V. Potentials in excess of 3.9 V cause an irreversible decrease in conductivity. Spin and charge show a 1:1 relation on/y to very low doping levels. Two paramagnetic species are produced on doping. A maximum spin concentration is observed at =3.7 V. The ultraviolet —visible —near-infrared spectra of doped PDMPV show at least five absorption bands, at 4.8, 3.7, 2.5, 1.7, and 0.6 eV. The first three bands decrease with doping and the latter two increase. When analyzed by the polaron or bipolaron model, the optical data imply significant symmetry breaking, Contributions to the optical activity from polarons and bipolarons are determined from the EPR results and are found to be di6'erent for both peaks, implying greater symmetrybreaking eA'ects for polarons. An electrochemical analysis of EPR results suggests that polaron interaction energies are =0.4S eV greater than those for bipolarons.
Show less - Date Issued
- 1989
- Identifier
- FSU_migr_chm_faculty_publications-0006
- Format
- Citation
- Title
- The "Demand Side" of General Education - A Review of the Literature: Technical Report Number 11.
- Creator
-
Reardon, Robert C, Lenz, Janet G, Sampson, James P, Johnston, Joseph S, Kramer, Gary L
- Abstract/Description
-
Much of the literature in general education is focused on the design or contents of the program, or the "supply side," while little attention has been given to students' understandings of and attitudes toward general education, the "demand side." This paper reviews literature on the "demand side" of general education by first providing a brief synopsis of the notion of general education and recent recommendations for reform, and next summarizing research on student knowledge of and attitudes...
Show moreMuch of the literature in general education is focused on the design or contents of the program, or the "supply side," while little attention has been given to students' understandings of and attitudes toward general education, the "demand side." This paper reviews literature on the "demand side" of general education by first providing a brief synopsis of the notion of general education and recent recommendations for reform, and next summarizing research on student knowledge of and attitudes toward higher education and general education. Because of the paucity of "demand side" research, the paper shifts focus to processes used in higher education to affect demand side questions, including teaching, recruitment and admissions, orientation, academic and career advising, and course scheduling. The paper ends with conclusions on the importance of attending to "demand side" issues in the improvement of general education programs.
Show less - Date Issued
- 1990-07-01
- Identifier
- FSU_libsubv1_scholarship_submission_1525887098_ce56a520, 10.17125/fsu.1525887098
- Format
- Citation
- Title
- Fermentation of trichoderma reesei and apparatus therefor.
- Creator
-
Cho, Michael Y.
- Abstract/Description
-
A process for producing enzyme cellulases by the fermentation of Trichoderma reesei in an aqueous nutrient medium containing assimilable sources of cellulose, nitrogen, phosphate, magnesium and iron in the presence of an oxygen containing atmosphere and a fermentation apparatus for the aerobic fermentation of microorganisms in a liquid medium at a pressure in excess of about 7 atmospheres. The method comprises fermenting the Trichoderma reesei at a temperature of between about 26.degree. C....
Show moreA process for producing enzyme cellulases by the fermentation of Trichoderma reesei in an aqueous nutrient medium containing assimilable sources of cellulose, nitrogen, phosphate, magnesium and iron in the presence of an oxygen containing atmosphere and a fermentation apparatus for the aerobic fermentation of microorganisms in a liquid medium at a pressure in excess of about 7 atmospheres. The method comprises fermenting the Trichoderma reesei at a temperature of between about 26.degree. C. and 31.degree. C. while maintaining the oxygen containing atmosphere at a pressure of about 1 atmosphere until the Trichoderma reesei enter the late stationary growth phase, thereafter, gradually and steadily increasing the pressure of the oxygen containing atmosphere until it is in excess of about 7 atmospheres and culturing the Trichoderma reesei at said increased pressure and at a temperature of between about 40.degree. C. and about 60.degree. C., thereby resulting in the production of enzyme cellulases by the Trichoderma reesei, and recovering the enzyme cellulases.
Show less - Date Issued
- 1990-08-28
- Identifier
- FSU_uspto_4952505, 4952505, 763646, 07/229823, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Holland's Theory and Effective Use of Computer-Assisted Career Guidance Systems: Technical Report No. 12.
- Creator
-
Lenz, Janet G, Reardon, Robert C, Sampson, James P
- Abstract/Description
-
A variety of client characteristics, drawn primarily from John Holland's theory and constructs, were used to examine client reactions to using a computer-assisted career guidance system. The subjects were 206 individuals who sought assistance at a university-based career center. A regression analysis revealed that persons with higher Social and Enterprising scores rated the system lower on its ability to help then acquire self and occupational knowledge.
- Date Issued
- 1991-10--1
- Identifier
- FSU_libsubv1_scholarship_submission_1525887511_b81ce3df, 10.17125/fsu.1525887511
- Format
- Citation
- Title
- Prospects for Using C60 and C70 in Lithium Batteries.
- Creator
-
Seger, L., Wen, L., Schlenoff, Joseph B.
- Abstract/Description
-
Solid films of C60 and C70 fullerenes are evaluated in propylene carbonate/lithium perchlorate, an electrolyte commonly used in lithium batteries. Cyclic voltammetry, chronopotentiometry, and an effusion test, show that reduced C60 and C70 are soluble in the electrolyte tested, which, coupled with poor stability of the highly reduced material and poor electrochemical reversibility, would compromise the performance of secondary batteries based on these fullerenes.
- Date Issued
- 1991
- Identifier
- FSU_migr_chm_faculty_publications-0005, 10.1149/1.2085516
- Format
- Citation
- Title
- Method for preparation of taxol using an oxazinone.
- Creator
-
Holton, Robert A.
- Abstract/Description
-
Process for the preparation of a taxol intermediate comprising contacting an alcohol with an oxazinone having the formula: ##STR1## wherein R.sub.1 is aryl, substituted aryl, alkyl, alkenyl, or alkynyl; R.sub.2 is hydrogen, ethoxyethyl, 2,2,2-trichloroethoxymethyl or other hydroxyl protecting group; and R.sub.3 is aryl, substituted aryl, alkyl, alkenyl, or alkynyl; the contacting of said alcohol and oxazinone being carried out in the presence of a sufficient amount of an activating agent...
Show moreProcess for the preparation of a taxol intermediate comprising contacting an alcohol with an oxazinone having the formula: ##STR1## wherein R.sub.1 is aryl, substituted aryl, alkyl, alkenyl, or alkynyl; R.sub.2 is hydrogen, ethoxyethyl, 2,2,2-trichloroethoxymethyl or other hydroxyl protecting group; and R.sub.3 is aryl, substituted aryl, alkyl, alkenyl, or alkynyl; the contacting of said alcohol and oxazinone being carried out in the presence of a sufficient amount of an activating agent under effective conditions to cause the oxazinone to react with the alcohol to form a .beta.-amido ester which is suitable for use as an intermediate in the synthesis of taxol.
Show less - Date Issued
- 1991-05-14
- Identifier
- FSU_uspto_5015744, 5015744, 711524, 07/436235, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Evolution of Physical and Electrochemical Properties of Polypyrrole during Extended Oxidation.
- Creator
-
Schlenoff, Joseph B., Xu, Hong
- Abstract/Description
-
The charge storage capacity and electrical conductivity of polypyrrole are followed through regimes of chemically reversible and irreversible electroactivity. Overoxidation of polypyrrole occurs at potentials in excess of 0.7 V vs. a saturated calomel electrode (SCE), as demonstrated by cyclic voltammetry of thin films. Material loss from polymer films as they are overoxidized is determined by in situ quartz microbalance experiments. The potential window for reversible electrochemistry in...
Show moreThe charge storage capacity and electrical conductivity of polypyrrole are followed through regimes of chemically reversible and irreversible electroactivity. Overoxidation of polypyrrole occurs at potentials in excess of 0.7 V vs. a saturated calomel electrode (SCE), as demonstrated by cyclic voltammetry of thin films. Material loss from polymer films as they are overoxidized is determined by in situ quartz microbalance experiments. The potential window for reversible electrochemistry in polypyrrole is compared to that for other conducting polymers. Reflectance FTIR of thick films reveals that hydroxyl groups, followed by carbonyls, result from overoxidation.
Show less - Date Issued
- 1992
- Identifier
- FSU_migr_chm_faculty_publications-0004, 10.1149/1.2221238
- Format
- Citation
- Title
- An Analysis of the Localization Feature of Two Computer-Assisted Career Guidance Systems - DISCOVER and SIGI PLUS: Technical Report No. 14.
- Creator
-
Lenz, Janet G, Leierer, Stephen J, Reardon, Robert C, Sampson, James P
- Abstract/Description
-
This report describes the efforts of the Career Center at Florida State University to implement the localization options in the DISCOVER and SIGI PLUS computer-assisted career guidance (CACG) systems in 1991-1992. A review of the literature and current use of localization suggested that it is a complex, underutilized extension of CACG software. Use of the localization feature raises issues about the nature of the desired client outcomes, the type of information to be included, the processes...
Show moreThis report describes the efforts of the Career Center at Florida State University to implement the localization options in the DISCOVER and SIGI PLUS computer-assisted career guidance (CACG) systems in 1991-1992. A review of the literature and current use of localization suggested that it is a complex, underutilized extension of CACG software. Use of the localization feature raises issues about the nature of the desired client outcomes, the type of information to be included, the processes and costs for installing and using the feature, and who in the organization should be responsible. To determine what types of information to include in localization, career advising staff were surveyed, two staff meetings were held, and user feedback on the two CACG systems were examined. It was decided to emphasize local information that would accomplish the goals of (1) providing instructions to improve client interaction with the CACGS and reduce client confusion, and (2) linking clients with other Career Center resources and activities. Primary localization efforts were directed toward DISCOVER because the software design was more compatible with the two program goals noted above. This report includes a discussion of project findings in relation to localization issues, i.e., clarifying the purposes of localization, the influences of system design on localization functioning, the impact of localization on CACG system effects, and the impact of localization on staffing and training. The report concludes with a review of implications for practitioners and system developers of the study of CACG system localization features.
Show less - Date Issued
- 1992-06-22
- Identifier
- FSU_libsubv1_scholarship_submission_1525888624_5df96194, 10.17125/fsu.1525888624
- Format
- Citation
- Title
- Method for preparation of taxol using an oxazinone.
- Creator
-
Holton, Robert A.
- Abstract/Description
-
Process for the preparation of a taxol intermediate comprising contacting an alcohol with an oxazinone having the formula: ##STR1## wherein R.sub.1 is aryl, heteroaryl, alkyl, alkenyl, alkynyl or OR.sub.7 wherein R.sub.7 is alkyl, alkenyl, alkynyl, aryl or heteroaryl; R.sub.2 and R.sub.5 are independently selected from hydrogen, alkyl alkenyl, alkynyl, aryl, heteroaryl, and OR.sub.8 wherein R.sub.8 is alkyl, alkenyl, alkynyl, aryl, heteroaryl, or hydroxyl protecting group; and R.sub.3 and R...
Show moreProcess for the preparation of a taxol intermediate comprising contacting an alcohol with an oxazinone having the formula: ##STR1## wherein R.sub.1 is aryl, heteroaryl, alkyl, alkenyl, alkynyl or OR.sub.7 wherein R.sub.7 is alkyl, alkenyl, alkynyl, aryl or heteroaryl; R.sub.2 and R.sub.5 are independently selected from hydrogen, alkyl alkenyl, alkynyl, aryl, heteroaryl, and OR.sub.8 wherein R.sub.8 is alkyl, alkenyl, alkynyl, aryl, heteroaryl, or hydroxyl protecting group; and R.sub.3 and R.sub.6 are independently selected from hydrogen, alkyl, alkenyl, alkynyl, aryl and heteroaryl.
Show less - Date Issued
- 1992-08-04
- Identifier
- FSU_uspto_5136060, 5136060, 711524, 07/603041, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Method for preparation of taxol using .beta.-lactam.
- Creator
-
Holton, Robert A.
- Abstract/Description
-
A .beta.-lactam of the formula: ##STR1## wherein R.sub.1 is aryl, substituted aryl, alkyl, alkenyl, or alkynyl; R.sub.2 is hydrogen, alkyl, acyl, acetal, ethoxyethyl, or other hydroxyl protecting group; and R.sub.3 is aryl, substituted aryl, alkyl, alkenyl, or alkynyl; and process for the preparation of taxol comprising contacting said .beta.-lactam and an alcohol in the presence of an activating agent to provide a taxol intermediate, and converting the intermediate to taxol.
- Date Issued
- 1992-12-29
- Identifier
- FSU_uspto_5175315, 5175315, 711524, 07/415028, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Hermetic Sample Housing for X-ray Diffraction Studies.
- Creator
-
Schlenoff, Joseph B., Rink, W. Jack, Mathias, H.
- Abstract/Description
-
A portable sample housing has been constructed for room-temperature powder geometry X-ray diffraction analysis of samples that are air or moisture sensitive. The housing can be easily handled in a glovebox, providing a means for direct loading and X-ray measurements on samples that should not be exposed to air or moisture after preparation. Its design allows adaptation to various makes of diffractometer that are limited to flat sample geometry. The design offers several improvements over...
Show moreA portable sample housing has been constructed for room-temperature powder geometry X-ray diffraction analysis of samples that are air or moisture sensitive. The housing can be easily handled in a glovebox, providing a means for direct loading and X-ray measurements on samples that should not be exposed to air or moisture after preparation. Its design allows adaptation to various makes of diffractometer that are limited to flat sample geometry. The design offers several improvements over existing technology, including the accommodation of large-area thin films and single crystals. Sample preparation and alignment in the X-ray beam have been found to be easy and efficient. The two-layer X-ray window of the device reduces the diffracted intensity by 40%, without any change in the relative intensities of the peaks in the spectrum.
Show less - Date Issued
- 1993
- Identifier
- FSU_migr_chm_faculty_publications-0012, 10.1107/S0021889893013822
- Format
- Citation
- Title
- Specimen holder.
- Creator
-
Rink, William J., Schlenoff, Joseph B., Mathias, Haim H.
- Abstract/Description
-
A specimen holder including a housing having a specimen chamber in it. A window defining a wall of the chamber allows transmission of at least a portion of the x-radiation from X-ray diffraction spectometry apparatus on which the holder is mounted, into the chamber. The housing has a passageway in it opening at one end into the specimen chamber and at the opposite end to outside the housing. A cylindrical specimen mount supports the specimen in the housing is constructed for sealing sliding...
Show moreA specimen holder including a housing having a specimen chamber in it. A window defining a wall of the chamber allows transmission of at least a portion of the x-radiation from X-ray diffraction spectometry apparatus on which the holder is mounted, into the chamber. The housing has a passageway in it opening at one end into the specimen chamber and at the opposite end to outside the housing. A cylindrical specimen mount supports the specimen in the housing is constructed for sealing sliding reception in the passageway such that the specimen mount is rotatable about its longitudinal axis and movable lengthwise of the passageway while maintaining a seal with the passageway for positioning the specimen in the specimen chamber.
Show less - Date Issued
- 1993-01-19
- Identifier
- FSU_uspto_5181233, 5181233, 915738, 07/790203, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Method for producing freestanding high Tc superconducting thin films.
- Creator
-
Ng, Hon-Kie, Kilibarda-Dalafave, Snezana
- Abstract/Description
-
A process for producing a freestanding high Tc superconducting thin film is disclosed, which comprises providing a carbon substrate, depositing a high Tc superconducting thin film on the substrate and removing the carbon substrate by converting the carbon substrate to a gaseous composition at a temperature insufficient to cause thermal damage to said superconducting thin film but greater then 500.degree. C. in an oxygen containing atmosphere.
- Date Issued
- 1993-02-16
- Identifier
- FSU_uspto_5187147, 5187147, 919692, 07/708186, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- The Financial Status, Organizational Structure, and Staffing of Career Information Delivery Systems in the United States: Technical Report No. 16.
- Creator
-
Sampson, James P, Norris, Debra S
- Abstract/Description
-
The purpose of this study was to collect, analyze, and disseminate baseline data to aid computer-based career information delivery system (CIDS) operators and state and federal policy makers in making more informed decisions about the financing, organizational structure, and staffing of CIDS. Lester and Ollis (1988) defined CIDS as "computer-based resources that provide information on occupations and related education and training opportunities" (p. 205). A total of 47 out of the 49 eligible...
Show moreThe purpose of this study was to collect, analyze, and disseminate baseline data to aid computer-based career information delivery system (CIDS) operators and state and federal policy makers in making more informed decisions about the financing, organizational structure, and staffing of CIDS. Lester and Ollis (1988) defined CIDS as "computer-based resources that provide information on occupations and related education and training opportunities" (p. 205). A total of 47 out of the 49 eligible CIDS returned the CIDS Information Collection Form, yielding a final response rate of 96%. Results are presented in 17 tables and 11 figures. The results are then discussed, including specific attention to implications for the future.
Show less - Date Issued
- 1993-03-01
- Identifier
- FSU_libsubv1_scholarship_submission_1525959154_e9f2b00a, 10.17125/fsu.1525959154
- Format
- Citation
- Title
- Furyl and thienyl substituted taxanes and pharmaceutical compositions containing them.
- Creator
-
Holton, Robert A., Nadizadeh, Hossain, Beidiger, Ronald J.
- Abstract/Description
-
A taxane derivative of the formula ##STR1## wherein ##STR2## Z is --OT.sub.1, T.sub.1 is hydrogen, hydroxyl protecting group, or --COT.sub.2, PA0 T.sub.2 is H, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkenyl, C.sub.1 -C.sub.6 alkynyl or monocylic aryl, PA0 R.sub.3 is benzoyl, substituted benzoyl or C.sub.1 -C.sub.6 alkoxycarbonyl, PA0 Ac is acetyl, and PA0 E.sub.1 and E.sub.2 are independently selected from hydrogen and functional groups which increase the water solubility of the taxane...
Show moreA taxane derivative of the formula ##STR1## wherein ##STR2## Z is --OT.sub.1, T.sub.1 is hydrogen, hydroxyl protecting group, or --COT.sub.2, PA0 T.sub.2 is H, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkenyl, C.sub.1 -C.sub.6 alkynyl or monocylic aryl, PA0 R.sub.3 is benzoyl, substituted benzoyl or C.sub.1 -C.sub.6 alkoxycarbonyl, PA0 Ac is acetyl, and PA0 E.sub.1 and E.sub.2 are independently selected from hydrogen and functional groups which increase the water solubility of the taxane derivative are useful as antitumor agents.
Show less - Date Issued
- 1993-07-13
- Identifier
- FSU_uspto_5227400, 5227400, 711524, 07/862819, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Metal alkoxides.
- Creator
-
Holton, Robert A.
- Abstract/Description
-
A metal alkoxide having the following formula: ##STR1## wherein T.sub.1 is hydrogen or a hydroxy protecting group, Z is --OT.sub.2, or --OCOCH.sub.3, T.sub.2 is hydrogen or a hydroxy protecting group, and M is selected from the group comprising Group IA, IIA and transition metals are useful in the preparation of biologically active derivatives of baccatin III and 10-deacetyl baccatin III.
- Date Issued
- 1993-07-20
- Identifier
- FSU_uspto_5229526, 5229526, 711524, 07/862778, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Certain alkoxy substituted taxanes and pharmaceutical compositions containing them.
- Creator
-
Holton, Robert A., Beidiger, Ronald J.
- Abstract/Description
-
A taxane derivative of the formula ##STR1## wherein R.sub.1 is phenyl or substituted phenyl, PA0 R.sub.3 is CH.sub.3 O--, or CH.sub.3 CH.sub.2 O--, PA0 Z is --OT.sub.1, PA0 T.sub.1 is hydrogen, hydroxyl protecting group, or --COT.sub.2. PA0 T.sub.2 is H, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkenyl, C.sub.1 -C.sub.6 alkynyl or monocylic aryl, PA0 Ac is acetyl, and PA0 E.sub.1 and E.sub.2 are independently selected from hydrogen and functional groups which increase the water solubility of...
Show moreA taxane derivative of the formula ##STR1## wherein R.sub.1 is phenyl or substituted phenyl, PA0 R.sub.3 is CH.sub.3 O--, or CH.sub.3 CH.sub.2 O--, PA0 Z is --OT.sub.1, PA0 T.sub.1 is hydrogen, hydroxyl protecting group, or --COT.sub.2. PA0 T.sub.2 is H, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkenyl, C.sub.1 -C.sub.6 alkynyl or monocylic aryl, PA0 Ac is acetyl, and PA0 E.sub.1 and E.sub.2 are independently selected from hydrogen and functional groups which increase the water solubility of the taxane derivative are useful as antitumor agents.
Show less - Date Issued
- 1993-09-07
- Identifier
- FSU_uspto_5243045, 5243045, 711524, 07/863198, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- The Impact of DISCOVER for Adult Learners and SIGI PLUS on the Career Decision Making of Adults Technical Report Number 9.
- Creator
-
Sampson, James P, Reardon, Robert C, Lenz, Janet G, Ryan-Jones, Rebecca E, Peterson, Gary W, Levy, Rick
- Abstract/Description
-
This study evaluated the effects of DISCOVER for Adult Learners and SIGI PLUS on career decidedness, vocational identity, and perceptions of computer use for 116 adults seeking services at a self-help oriented career center. Adults were randomly assigned to either DISCOVER for Adult Learners (DAL), SIGI PLUS, or a control condition that involved unstructured use of print and AV materials in a university career center. Use of DAL and SIGI PLUS by adults resulted in positive gains in vocational...
Show moreThis study evaluated the effects of DISCOVER for Adult Learners and SIGI PLUS on career decidedness, vocational identity, and perceptions of computer use for 116 adults seeking services at a self-help oriented career center. Adults were randomly assigned to either DISCOVER for Adult Learners (DAL), SIGI PLUS, or a control condition that involved unstructured use of print and AV materials in a university career center. Use of DAL and SIGI PLUS by adults resulted in positive gains in vocational identity. Subjects in the control condition and subjects using DISCOVER experienced a significant increase in career decidedness. Adults perceived both systems as having a positive impact on three dimensions of computer effectiveness, Analysis, Synthesis, and Computer Effect. The conclusion was that computer-based interventions are equivalent to more traditional career interventions. Implications of these results for practice and further research are discussed.
Show less - Date Issued
- 1993-10-01
- Identifier
- FSU_libsubv1_scholarship_submission_1525886209_752378bb, 10.17125/fsu.1525886209
- Format
- Citation
- Title
- Improving Career Services and Research with the Computer Version of the Self-Directed Search (Form R): Technical Report Number 15.
- Creator
-
Reardon, Robert C, Lenz, Janet G, Strausberger, Scott J
- Abstract/Description
-
The purpose of this study was to examine the use of the Self-Directed Search: Computer Version (SDS:CV) in a university career center's service delivery and research activities. Data were collected from a sample fo 180 clients over a 16 month period, using the information provided in the professional summary report of the SDS:CV. Social and Enterprising types were the most common client codes (57%), and the mean Vocational Identity score from the My Vocational Situation was 5.26. Additional...
Show moreThe purpose of this study was to examine the use of the Self-Directed Search: Computer Version (SDS:CV) in a university career center's service delivery and research activities. Data were collected from a sample fo 180 clients over a 16 month period, using the information provided in the professional summary report of the SDS:CV. Social and Enterprising types were the most common client codes (57%), and the mean Vocational Identity score from the My Vocational Situation was 5.26. Additional data about the client group was examined regarding the secondary constructs from Holland's theory of congruence (expressed vs. assessed Holland codes), differentiation, consistency, commonness, need for information, and vocational choice barriers. Low vocational identity items endorsed by 80% of the clients were also identified. An analysis of cost information for software and staff resources indicated that the SDS:CV was used at a cost of $10.10 per client in this setting. Discussion focused on the application of research information provided by the SDS:CV in designing career interventions, using the secondary constructs in career counseling, developing outreach programs, comparing and contrasting the paper and computer versions of the SDS, and the use of theory-based career interventions.
Show less - Date Issued
- 1993-10-01
- Identifier
- FSU_libsubv1_scholarship_submission_1525889460_6ee435da, 10.17125/fsu.1525889460
- Format
- Citation
- Title
- Certain substituted taxanes and pharmaceutical compositions containing them.
- Creator
-
Holton, Robert A., Nadizadeh, Hossain, Beidiger, Ronald J., Kim, Seokchan
- Abstract/Description
-
A taxane derivative of the formula ##STR1## wherein R.sub.1 and R.sub.3 are independently selected from the group comprising phenyl, naphthalene, C.sub.6 H.sub.5 CHCH--, and ##STR2## provided, however, R.sub.1 and R.sub.3 are not both phenyl; PA0 Q is CH.sub.3 --, (CH.sub.3).sub.3 C--, CH.sub.3 O--, Cl, Br, F, NO.sub.2, ##STR3## Z is --OT.sub.1, T.sub.1 is hydrogen, hydroxyl protecting group, or --COT.sub.2, PA0 T.sub.2 is H, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkenyl, C.sub.1 -C.sub.6...
Show moreA taxane derivative of the formula ##STR1## wherein R.sub.1 and R.sub.3 are independently selected from the group comprising phenyl, naphthalene, C.sub.6 H.sub.5 CHCH--, and ##STR2## provided, however, R.sub.1 and R.sub.3 are not both phenyl; PA0 Q is CH.sub.3 --, (CH.sub.3).sub.3 C--, CH.sub.3 O--, Cl, Br, F, NO.sub.2, ##STR3## Z is --OT.sub.1, T.sub.1 is hydrogen, hydroxyl protecting group, or --COT.sub.2, PA0 T.sub.2 is H, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkenyl, C.sub.1 -C.sub.6 alkynyl or monocylic aryl, PA0 Ac is acetyl, and PA0 E.sub.1 and E.sub.2 are independently selected from hydrogen and functional groups which increase the water solubility of the taxane derivative are useful as antitumor agents.
Show less - Date Issued
- 1993-10-05
- Identifier
- FSU_uspto_5250683, 5250683, 711524, 07/863451, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Semi-synthesis of taxane derivatives using metal alkoxides and oxazinones.
- Creator
-
Holton, Robert A.
- Abstract/Description
-
A process for preparing taxane derivatives taxol by providing a metal alkoxide having the bi, tri-, or tetracyclic taxane nucleus, reacting the metal alkoxide with an oxazinone to form an intermediate, and converting the intermediate to the taxane derivative.
- Date Issued
- 1993-10-19
- Identifier
- FSU_uspto_5254703, 5254703, 711524, 07/863829, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Low self-absorbing, intrinsically scintillating polymers.
- Creator
-
Schlenoff, Joseph B., Dharia, Jayesh, Johnson, Kurtis F.
- Abstract/Description
-
Polymers containing covalently-bonded, low self-absorbing, scintillating chromophores, polymerizable chromophores of the formula: ##STR1## wherein R.sub.1 is vinyl, .alpha.-methyl vinyl, vinyl phenyl, or vinyl benzyl, and R.sub.2 and R.sub.3 are independently hydrogen, alkyl, aryl, cyano, nitro, halo, or ether, and a process for the preparation of polymers containing low self-absorbing, scintillating chromophores.
- Date Issued
- 1993-11-02
- Identifier
- FSU_uspto_5258478, 5258478, 915739, 07/874748, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Current Status and Future Potential for Evaluating the Design and Use of Computer-Based Career Information Delivery Systems in the United States: Technical Report Number 17.
- Creator
-
Sampson, James P
- Abstract/Description
-
Career information delivery systems (CIDS) are an increasingly common resource for the delivery of information to individuals involved in making career and educational choices. This paper is intended to stimulate further discussion of improving CIDS evaluation, ultimately leading to further refinement of ACSCI/NOICC evaluation guidelines. This paper is also intended to support the current effort to evaluate CIDS use in employment services. The term evaluation ,as used in this paper, includes...
Show moreCareer information delivery systems (CIDS) are an increasingly common resource for the delivery of information to individuals involved in making career and educational choices. This paper is intended to stimulate further discussion of improving CIDS evaluation, ultimately leading to further refinement of ACSCI/NOICC evaluation guidelines. This paper is also intended to support the current effort to evaluate CIDS use in employment services. The term evaluation ,as used in this paper, includes both an objective description of current CIDS use and judgements about the appropriateness of CIDS use in relation to client needs. The paper begins by reviewing current efforts to evaluate CIDS, and continues with limitation of current CIDS evaluation efforts, recommendations for improved CIDS evaluation, and concludes with potential common survey data elements for CIDS evaluation.
Show less - Date Issued
- 1993-12-20
- Identifier
- FSU_libsubv1_scholarship_submission_1525960033_85211e82, 10.17125/fsu.1525960033
- Format
- Citation
- Title
- Metal alkoxides.
- Creator
-
Holton, Robert A.
- Abstract/Description
-
A metal alkoxide having the following formula: ##STR1## wherein T.sub.1 is hydrogen or a hydroxy protecting group, Z is --OT.sub.2, or --OCOCH.sub.3, T.sub.2 is hydrogen or a hydroxy protecting group, and M is selected from the group comprising Group IA, IIA and transition metals are useful in the preparation of biologically active derivatives of baccatin III and 10-deacetyl baccatin III.
- Date Issued
- 1993-12-28
- Identifier
- FSU_uspto_5274124, 5274124, 711524, 07/949066, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Furyl or thienyl carbonyl substituted taxanes and pharmaceutical compositions containing them.
- Creator
-
Holton, Robert A., Nadizadeh, Hossain, Rengan, Kasthuri
- Abstract/Description
-
Taxane derivatives of the formula ##STR1## wherein R.sub.1 is phenyl or p-nitrophenyl, PA1 R.sub.3 is furyl or thienyl, PA1 T.sub.1 is hydrogen, hydroxyl protecting group, or --COT.sub.2, PA1 T.sub.2 is H, C.sub.1 -C.sub.6 alkyl, C.sub.2 -C.sub.6 alkenyl, C.sub.2 -C.sub.6 alkynyl or monocylic aryl, PA1 Ac is acetyl, and PA1 E.sub.1 and E.sub.2 are independently selected from hydrogen and functional groups which increase the water solubility of the taxane derivative are useful as antitumor...
Show moreTaxane derivatives of the formula ##STR1## wherein R.sub.1 is phenyl or p-nitrophenyl, PA1 R.sub.3 is furyl or thienyl, PA1 T.sub.1 is hydrogen, hydroxyl protecting group, or --COT.sub.2, PA1 T.sub.2 is H, C.sub.1 -C.sub.6 alkyl, C.sub.2 -C.sub.6 alkenyl, C.sub.2 -C.sub.6 alkynyl or monocylic aryl, PA1 Ac is acetyl, and PA1 E.sub.1 and E.sub.2 are independently selected from hydrogen and functional groups which increase the water solubility of the taxane derivative are useful as antitumor agents.
Show less - Date Issued
- 1994-02-01
- Identifier
- FSU_uspto_5283253, 5283253, 711524, 07/975723, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Butenyl substituted taxanes and pharmaceutical compositions containing them.
- Creator
-
Holton, Robert A., Nadizadeh, Hossain
- Abstract/Description
-
Taxane derivatives of the formula ##STR1## wherein R.sub.1 is butenyl, PA0 R.sub.3 is phenyl, PA0 T.sub.1 is hydrogen, hydroxyl protecting group, or --COT.sub.2, PA0 T.sub.2 is H, C.sub.1 -C.sub.6 alkyl, C.sub.2 -C.sub.6 alkenyl, C.sub.2 -C.sub.6 alkynyl or monocylic aryl, PA0 Ac is acetyl, and PA0 E.sub.1 and E.sub.2 are independently selected from hydrogen and functional groups which increase the water solubility of the taxane derivative are useful as antitumor agents.
- Date Issued
- 1994-02-08
- Identifier
- FSU_uspto_5284864, 5284864, 711524, 07/975705, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Superconductive alloys having bifurcated critical current density and method of preparation.
- Creator
-
Testardi, Louis R., Hascicek, Yusuf S.
- Abstract/Description
-
A device having superconductive and resistive states including an element comprising a high temperature superconductive material having a first (high) state with a first (high) critical current density and having a second (low) state with a second (low) critical current density, wherein the second (low) critical current density is less than the first (high) critical current density. A transient pulse generator applies a transient pulse to the element. The transient pulse changes the state of...
Show moreA device having superconductive and resistive states including an element comprising a high temperature superconductive material having a first (high) state with a first (high) critical current density and having a second (low) state with a second (low) critical current density, wherein the second (low) critical current density is less than the first (high) critical current density. A transient pulse generator applies a transient pulse to the element. The transient pulse changes the state of the element between the first (high) and second (low) states, the element being superconductive in the first (high) state, and the element being resistive in the second (low) state. A YBa.sub.2 Cu.sub.3 O.sub.7-x or YBa.sub.2 Cu.sub.3 O.sub.7-x -Ag compound exhibiting bifurcation of its critical current density versus temperature curve. A process for the production of a YBa.sub.2 Cu.sub.3 O.sub.7-x or YBa.sub.2 Cu.sub.3 O.sub.7-x -Ag superconducting material which exhibits bifurcation in its critical current density versus temperature curve. The process involves the provision of the appropriate powder or mix of powders, pressing the powder to form the desired specimen, sintering the specimen at a sufficient temperature for a sufficient time to achieve fusion of the powder, heat treating the sintered specimen, and subjecting the specimen to an oxygenation process.
Show less - Date Issued
- 1994-02-15
- Identifier
- FSU_uspto_5286710, 5286710, 846000, 07/644175, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Potential Contributions of Career Information Delivery Systems to One-Stop Career Centers, Military Downsizing, and School-to-Work Transition Initiatives: Technical Report Number 18.
- Creator
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Sampson, James P, Reardon, Robert C, Norris, Debra S, Wilde, Caroline K, Dietrich, Eleanor
- Abstract/Description
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This report documents an effort by the Association of Computer-Based Systems for Career Information to facilitate increased awareness and utilization of career information delivery systems (CIDS) by federal, state, and local governmental agencies who plan and deliver career services for adults and adolescents in transition. By more clearly understanding how CIDS specifically contribute to recent federal initiatives related to one-stop career centers, military downsizing, and school to work...
Show moreThis report documents an effort by the Association of Computer-Based Systems for Career Information to facilitate increased awareness and utilization of career information delivery systems (CIDS) by federal, state, and local governmental agencies who plan and deliver career services for adults and adolescents in transition. By more clearly understanding how CIDS specifically contribute to recent federal initiatives related to one-stop career centers, military downsizing, and school to work transitions, CIDS operators can be more proactive in ensuring that CIDS are used to the fullest extent possible in meeting the transition needs of adults and adolescents in the United States. The planning activity outlined in this report incorporates the collective experience and judgement of professionals experienced with CIDS design and use. Individuals invited to participate in the planning activity included all attendees of the Association of Computer-Based Systems for Career Information 16th annual conference held December 1-3, 1993, in Nashville, Tennessee. Using a nominal group technique, facilitators assisted two groups of randomly assigned conference participants in exploring how CIDS could contribute to one-stop career centers, military downsizing, and school-to-work transitions. Each group developed lists of potential CIDS contributions in priority order that are presented in a series of tables. Comments from conference participants regarding trends across the priorities identified by each group and potential next steps in planning are also included. The report concludes with a recommendation for a content analysis of potential CIDS contributions.
Show less - Date Issued
- 1994-06-08
- Identifier
- FSU_libsubv1_scholarship_submission_1525961106_7815871f, 10.17125/fsu.1525961106
- Format
- Citation
- Title
- Method for preparation of taxol.
- Creator
-
Holton, Robert A.
- Abstract/Description
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A .beta.-lactam of the formula: ##STR1## wherein R.sub.1 is aryl, substituted aryl, alkyl, alkenyl, or alkynyl; R.sub.2 is hydrogen, alkyl, acyl, acetal, ethoxyethyl, or other hydroxyl protecting group; and R.sub.3 is aryl, substituted aryl, alkyl, alkenyl, or alkynyl; and process for the preparation of taxol comprising contacting said .beta.-lactam and an alcohol in the presence of an activating agent to provide a taxol intermediate, and converting the intermediate to taxol.
- Date Issued
- 1994-08-09
- Identifier
- FSU_uspto_5336785, 5336785, 711524, 07/968003, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Process for the preparation of 10-desacetoxybaccatin III and 10-desacetoxytaxol and derivatives thereof.
- Creator
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Holton, Robert A., Somoza, Carmen
- Abstract/Description
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A process for the preparation of a 10-desacetoxy and 10-desoxy tetracyclic taxane in which a tetracyclic taxane having a C10 hydroxy or acetoxy substituent is reacted with samarium diiodide.
- Date Issued
- 1994-08-16
- Identifier
- FSU_uspto_5338872, 5338872, 711524, 08/005229, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- 10-desacetoxytaxol derivatives.
- Creator
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Farina, Vittorio, Holton, Robert A., Chen, Shu-Hui
- Abstract/Description
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The present invention relates to 10-desacetoxytaxol and derivatives thereof, which are useful as antitumor agents. These compounds have the formula ##STR1## wherein R.sub.2 is hydrogen, hydroxy or a protected hydroxy group; R.sub.3 and R.sub.4 are independently hydrogen, hydroxy, a protected hydroxy group, methyl, --SH, --NH.sub.2, or --NR.sub.8 R.sub.9 ; R.sub.5 is R.sub.10, or --OR.sub.10 ; R.sub.6 and R.sub.7 are independently hydrogen, alkyl, or aryl; R.sub.8 and R.sub.9 are independently...
Show moreThe present invention relates to 10-desacetoxytaxol and derivatives thereof, which are useful as antitumor agents. These compounds have the formula ##STR1## wherein R.sub.2 is hydrogen, hydroxy or a protected hydroxy group; R.sub.3 and R.sub.4 are independently hydrogen, hydroxy, a protected hydroxy group, methyl, --SH, --NH.sub.2, or --NR.sub.8 R.sub.9 ; R.sub.5 is R.sub.10, or --OR.sub.10 ; R.sub.6 and R.sub.7 are independently hydrogen, alkyl, or aryl; R.sub.8 and R.sub.9 are independently hydrogen, alkyl, alkenyl, alkynyl, or aryl; and R.sub.10 is alkoxy, alkyl, alkenyl, alkynl, or aryl.
Show less - Date Issued
- 1994-09-27
- Identifier
- FSU_uspto_5350866, 5350866, 691280, 07/949449, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Numerical Simulation of the Cyclic Voltammogram of Polyacetylene.
- Creator
-
Diess, E., Haas, O., Schlenoff, Joseph B.
- Abstract/Description
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The measured cyclic voltammogram of a polyacety]ene-coated electrode bathed in an electrolyte solution was simulated numerically for various scan rates. The model used accounts for a modified Butler-Vo]mer-type heterogeneous kinetics at the electrode surface including a lateral interaction term which effects the observed hysteresis behavior. Within the polymer an electron flux obeying Ohm's law as well as electrolyte diffusion and migration is considered and Poisson's equation holds for...
Show moreThe measured cyclic voltammogram of a polyacety]ene-coated electrode bathed in an electrolyte solution was simulated numerically for various scan rates. The model used accounts for a modified Butler-Vo]mer-type heterogeneous kinetics at the electrode surface including a lateral interaction term which effects the observed hysteresis behavior. Within the polymer an electron flux obeying Ohm's law as well as electrolyte diffusion and migration is considered and Poisson's equation holds for electroneutrality. Donnan partition kinetics describes the flux and potential at the interface between the polymer and diffusion layer. Electrolyte diffusion is considered in the diffusion layer.
Show less - Date Issued
- 1995
- Identifier
- FSU_migr_chm_faculty_publications-0003, 10.1149/1.2049971
- Format
- Citation
- Title
- Oxazinone compounds for the preparation of taxol.
- Creator
-
Holton, Robert A.
- Abstract/Description
-
Process for the preparation of a taxol intermediate comprising contacting an alcohol with an oxazinone having the formula: ##STR1## wherein R.sub.1 is aryl, heteroaryl, alkyl, alkenyl, alkynyl or OR.sub.7 wherein R.sub.7 is alkyl, alkenyl, alkynyl, aryl or heteroaryl; R.sub.2 and R.sub.5 are independently selected from hydrogen, alkyl alkenyl, alkynyl, aryl, heteroaryl, and OR.sub.8 wherein R.sub.8 is alkyl, alkenyl, alkynyl, aryl, heteroaryl, or hydroxyl protecting group; and R.sub.3 and R...
Show moreProcess for the preparation of a taxol intermediate comprising contacting an alcohol with an oxazinone having the formula: ##STR1## wherein R.sub.1 is aryl, heteroaryl, alkyl, alkenyl, alkynyl or OR.sub.7 wherein R.sub.7 is alkyl, alkenyl, alkynyl, aryl or heteroaryl; R.sub.2 and R.sub.5 are independently selected from hydrogen, alkyl alkenyl, alkynyl, aryl, heteroaryl, and OR.sub.8 wherein R.sub.8 is alkyl, alkenyl, alkynyl, aryl, heteroaryl, or hydroxyl protecting group; and R.sub.3 and R.sub.6 are independently selected from hydrogen, alkyl, alkenyl, alkynyl, aryl and heteroaryl.
Show less - Date Issued
- 1995-01-24
- Identifier
- FSU_uspto_5384399, 5384399, 711524, 07/898438, 600b83161da1122888348587dc18798c
- Format
- Citation
- Title
- Process for the preparation of baccatin III analogs bearing new C2 and C4 functional groups.
- Creator
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Holton, Robert A., Kim, Seokchan
- Abstract/Description
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Process for the preparation of a derivative or analog of baccatin III or 10-desacetyl baccatin III having a C2 substituent other than benzoate and/or a C4 substituent other than acetate in which the C2 benzoate substituent and/or the C4 acetate substituent of a derivative of baccatin III or 10-desacetyl baccatin III is/are selectively reduced to the corresponding hydroxy group(s) and converted to R.sub.7 COO- and/or R.sub.8 COO-, respectively, wherein R.sub.7 and R.sub.8 are independently H,...
Show moreProcess for the preparation of a derivative or analog of baccatin III or 10-desacetyl baccatin III having a C2 substituent other than benzoate and/or a C4 substituent other than acetate in which the C2 benzoate substituent and/or the C4 acetate substituent of a derivative of baccatin III or 10-desacetyl baccatin III is/are selectively reduced to the corresponding hydroxy group(s) and converted to R.sub.7 COO- and/or R.sub.8 COO-, respectively, wherein R.sub.7 and R.sub.8 are independently H, C.sub.1 -C.sub.6 alkyl, C.sub.2 -C.sub.6 alkenyl, C.sub.2 -C.sub.6 alkynyl, moncyclic aryl, or monocyclic heteroaryl.
Show less - Date Issued
- 1995-03-21
- Identifier
- FSU_uspto_5399726, 5399726, 711524, 08/010798, 600b83161da1122888348587dc18798c
- Format
- Citation